STP conditions imply a temperature of 273.15 K and a pressure of 100 kPa. When tose conditions are met, 1 mole of any ideal gas will have a volume of 22.7 L. So, if 1 mole occupies a volume of 22.7 L, 2 moles will occupy a volume twice as big. Likewise, 0.5 moles will occupy half the volume 1 mole occupies.
